{"id":82,"date":"2021-11-15T16:00:59","date_gmt":"2021-11-15T16:00:59","guid":{"rendered":"https:\/\/blogs.ncl.ac.uk\/matthewhopkinson\/?page_id=82"},"modified":"2026-03-11T10:56:37","modified_gmt":"2026-03-11T10:56:37","slug":"publications","status":"publish","type":"page","link":"https:\/\/blogs.ncl.ac.uk\/matthewhopkinson\/publications\/","title":{"rendered":"Publications"},"content":{"rendered":"\n

55. Maximizing the benefits of competition: combining CHEMmunicate with post-game quizzes to support undergraduate students\u2019 learning of organic chemistry<\/strong>
C. Navarro,* M. N. Hopkinson*
Chem. Teach. Int. <\/em>2026<\/strong>, DOI: 10.1515\/cti-2026-0005.<\/p>\n\n\n

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54. A General Group Testing Strategy for Discovering Chemical Cooperativity<\/strong>
P. M. Pfl\u00fcger, F. Katzenburg, F. Sandfort, M. Teders, A. G\u00f3mez-Su\u00e1rez, E. A. Standley, M. N. Hopkinson, C. G. Daniliuc, A. Heuer*, F. Glorius*
Angew. Chem. Int. Ed. <\/em>2026<\/strong>, 65<\/em>, e25278.<\/p>\n\n\n

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53. A Reductive Mechanochemical Approach Enabling Direct Upcycling of Fluoride from Polytetrafluoroethylene (PTFE) into Fine Chemicals<\/strong>
M. E. Lowe, B. M. Gallant, N. Davison, M. N. Hopkinson, D. J. Kubicki,* E. Lu,* R. J. Armstrong*
J. Am. Chem. Soc. <\/em>2025<\/strong>, 147<\/em>, 40895\u201340899.<\/p>\n\n\n

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52. Photochemical reduction of acylimidazolium salts<\/strong>
M. Jakob, N. Bechler, H. Abdelwahab, F. Weber, J. Wasternack, L. Kleebauer, J. P. G\u00f6tze, M. N. Hopkinson*
Beilstein J. Org. Chem.<\/em> 2025,<\/strong> 21,<\/em> 1973\u20131983.
(Part of the thematic issue \u201cModern radical chemistry\u201d; Guest Editor: Prof. H.-M. Huang).<\/p>\n\n\n\n

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51. C=O Methylenation mediated by organo-alkali metal reagents: metal identity and ligand effects<\/strong>
X. Yang, N. Davison,* M. E. Lowe, P. G. Waddell, R. J. Armstrong,* C. L. McMullin,* M. N. Hopkinson, E. Lu*
Chem. Sci. <\/em>2025<\/strong>, 16<\/em>, 11151\u201311160.<\/p>\n\n\n

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50. CHEMmunicate: A chemical structure drawing game for building scientific communications skills and enhancing social interactions among first year undergraduate students<\/strong>
C. Navarro,* M. N. Hopkinson*
J. Chem. Educ. <\/em>2025<\/strong>, 102<\/em>, 1839\u20131847.<\/p>\n\n\n

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49. Dual N-Heterocyclic Carbene\/Photoredox-Catalyzed Coupling of Acyl Fluorides and Alkyl Silanes<\/strong><\/strong>
M. Jakob, L. Steiner, M. G\u00f6bel, J. P. G\u00f6tze, M. N. Hopkinson*
ACS Catal.<\/em> 2024<\/strong>, 14<\/em>, 17642\u201317653.<\/p>\n\n\n

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48. Direct Synthesis of Acyl Fluorides from Carboxylic Acids using Benzothiazolium Reagents<\/strong><\/strong>
L. M. Maas,\u2020 A. Haswell,\u2020 R. Hughes, M. N. Hopkinson*
Beilstein J. Org. Chem.<\/em> 2024<\/strong>, 20<\/em>, 921-930.
(Part of the thematic issue \u201cOrgano-fluorine Chemistry VI\u201d; Guest Editor: Prof. D. O\u2019Hagan).<\/p>\n\n\n

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47. C\u2212F Bond Insertion: An Emerging Strategy for Constructing Fluorinated Molecules<\/strong>
A. Garg, A. Haswell, M. N. Hopkinson*
Chem. Eur. J.<\/em> 2024<\/strong>, 30<\/em>, e202304229.<\/p>\n\n\n

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46. Catalyst-Free Trifluoromethoxylation of Silyl Enol Ethers and Allyl Silanes with Bis(trifluoromethyl)peroxide<\/strong>
L. M. Maas, C. Fasting, P. Vo\u00dfnacker, N. Limberg, P. Golz, C. M\u00fcller, S. Riedel,* M. N. Hopkinson*
Angew. Chem. Int. Ed. <\/em>2024<\/strong>, 63<\/em>, e202317770.
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45. Deoxygenative Perfluoroalkylthiolation of Carboxylic Acids with Benzothiazolium Reagents<\/strong>
A. Haswell, M. Tironi, H. Wang, M. N. Hopkinson*
J. Fluorine Chem.<\/em> 2024<\/strong>, 273<\/em>, 110231.
(Part of the Special Issue honouring Prof. Dr. Beate Koksch, Freie Universit\u00e4t Berlin \u2013 Recipient of the 2021 American Chemical Society Award for Creative Work in Fluorine Chemistry; Editor: J. Thrasher).<\/p>\n\n\n

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44. Formal Insertion of Alkenes Into C(sp3<\/sup><\/em>)\u2212F Bonds Mediated by Fluorine-Hydrogen Bonding<\/strong>
A. Garg, N. J. Gerwien, C. Fasting, A. Charlton, M. N. Hopkinson*
Angew. Chem. Int. Ed.<\/em> 2023<\/strong>, 62<\/em>, e202302860.
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43. A (TD-)DFT Study on Photo-NHC-Catalysis: Photoenolization\/Diels-Alder Reaction of Acid Fluorides Catalyzed by N-Heterocyclic Carbenes<\/strong>
A. Mavroskoufis, M. Lohani, M. Weber, M. N. Hopkinson,* J. P. G\u00f6tze*
Chem. Sci.<\/em> 2023<\/strong>, 14<\/em>, 4027-4037.<\/p>\n\n\n

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42. Silver-Catalyzed Nucleophilic Deoxydifluoromethylthiolation of Activated Aliphatic Alcohols with BT-SCF2<\/sub>H<\/strong>
M. Tironi, M. N. Hopkinson*
Eur. J. Org. Chem.<\/em> 2022<\/strong>, e202101557.<\/p>\n\n\n

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41. Activation of Tetrahydrofuran with 2-((Fluoroalkyl)thio)Benzothiazolium Reagents<\/strong>
L. M. Maas, J. R. Schmid, C. Fasting, P. Vo\u00dfnacker, A. Mavroskoufis, M. N. Hopkinson*
Tetrahedron<\/em> 2021<\/strong>, 101<\/em>, 132512.
(Part of the article collection “Fluorine and Chalcogens”; Guest Editors: E. Magnier & G. Dagousset).<\/p>\n\n\n

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40. Norrish Type II Reactions of Acyl Azolium Salts<\/strong>
A. Mavroskoufis, A. Rieck, M. N. Hopkinson*
Tetrahedron<\/em> 2021<\/strong>, 100<\/em>, 132497.
(Part of the article collection “System-Oriented Development of Organocatalysis”; Guest Editor: H. Ohmiya)<\/p>\n\n\n

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39. Deoxygenative Nucleophilic Difluoromethylselenylation of Carboxylic Acids and Alcohols with BT-SeCF2<\/sub>H<\/strong>
M. Tironi, S. Dix, M. N. Hopkinson*
Org. Chem. Front.<\/em> 2021<\/strong>, 8<\/em>, 6026-6031.<\/p>\n\n\n

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38. Recent advances in the chemistry and applications of N-heterocyclic carbenes<\/strong>
P. Bellotti, M. Koy, M. N. Hopkinson,* F. Glorius*
Nat. Rev. Chem.<\/em> 2021<\/strong>, 5<\/em>, 711-725.<\/p>\n\n\n

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37. Radical C-H Trifluoromethoxylation of (Hetero)arenes with Bis(trifluoromethyl)peroxide
<\/strong>S. Dix, P. Golz, J. R. Schmid, S. Riedel,* M. N. Hopkinson*
Chem. Eur. J.<\/em> 2021<\/strong>, 27<\/em>, 11554-11558.
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36. Benzothiazolium Salts as Reagents for the Deoxygenative Perfluoroalkylthiolation of Alcohols<\/strong>
A. Ariamajd,\u2020 N. J. Gerwien,\u2020 B. Schwabe, S. Dix, M. N. Hopkinson*
Beilstein J. Org. Chem.<\/em> 2021<\/strong>, 17<\/em>, 83-88.
(Part of the thematic issue “Organo-fluorine chemistry V”; Guest Editor: D. O’Hagan)<\/p>\n\n\n

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35. Deoxygenative Tri- and Difluoromethylthiolation of Carboxylic Acids with Benzothiazolium Reagents<\/strong>
M. Tironi,\u2020 L. M. Maas,\u2020 A. Garg, S. Dix, J. P. G\u00f6tze, M. N. Hopkinson*
Org. Lett.<\/em> 2020<\/strong>, 22<\/em>, 8925-8930.<\/p>\n\n\n

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34. Photo-NHC Catalysis: Accessing Ketone Photochemistry with Carboxylic Acid Derivatives<\/strong>
M. N. Hopkinson,* A. Mavroskoufis
Synlett<\/em> 2021<\/strong>, 32<\/em>, 95-101.<\/p>\n\n\n

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33. Light-Promoted Organocatalysis with N-Heterocyclic Carbenes
<\/strong>A. Mavroskoufis, M. Jakob, M. N. Hopkinson*
ChemPhotoChem<\/em> 2020<\/strong>, 4<\/em>, 5147-5153.<\/p>\n\n\n

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32. Synthesis of Trifluoromethylthiolated Alkenes and Alkynes<\/strong>
M. N. Hopkinson
In Emerging Fluorinated Motifs: Synthesis, Properties and Applications (Eds. D. Cahard, J.-A. Ma); Wiley-VCH: Weinheim, 2020, Volume 2, Chapter 14.<\/p>\n\n\n

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31. N-Heterocyclic Carbene Catalyzed Photoenolization\/Diels-Alder Reaction of Acid Fluorides<\/strong>
A. Mavroskoufis, K. Rajes, P. Golz, A. Agrawal, V. Ru\u00df, J. P. G\u00f6tze, M. N. Hopkinson*
Angew. Chem. Int. Ed.<\/em> 2020<\/strong>, 59<\/em>, 3190-3194; Angew. Chem.<\/em> 2020<\/strong>, 132<\/em>, 3216-3220.<\/p>\n\n\n

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30. Deoxytrifluoromethylthiolation and Selenylation of Alcohols by using Benzothiazolium Reagents<\/strong>
S. Dix, M. Jakob, M. N. Hopkinson*
Chem. Eur. J.<\/em> 2019<\/strong>, 25<\/em>, 7635-7639.<\/p>\n\n\n

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29. An Overview of NHCs<\/strong>
M. N. Hopkinson, F. Glorius
In N-Heterocyclic Carbenes in Organocatalysis (Ed. A. T. Biju); Wiley-VCH: Weinheim, 2019, Chapter 1, p. 1-36.<\/p>\n\n\n

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28. Gold in Photocatalysis<\/strong>
S. Dix, M. N. Hopkinson
In Science of Synthesis: Photocatalysis in Organic Synthesis (Ed. B. K\u00f6nig); Thieme: Stuttgart, (2018), Chapter 9.<\/p>\n\n\n

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27. A Radical Revolution for Trifluoromethoxylation<\/strong>
B. Sahoo, M. N. Hopkinson*
Angew. Chem. Int. Ed. <\/em>2018<\/strong>, 57<\/em>, 7942-7944; Angew. Chem.<\/em> 2018<\/strong>, 130<\/em>, 8070-8072.<\/p>\n\n\n

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Pre-Independent Career (Master, PhD & Postdoc)<\/strong><\/p>\n\n\n\n

26. Diverse Visible-Light-Promoted Functionalizations of Benzotriazoles Inspired by Mechanism-Based Luminescence Screening
<\/strong>M. Teders, A. G\u00f3mez-Su\u00e1rez, L. Pitzer, M. N. Hopkinson, F. Glorius*
Angew. Chem. Int. Ed. <\/em>2017<\/strong>, 56<\/em>, 902-906; Angew. Chem.<\/em> 2017<\/strong>, 129<\/em>, 921-925.
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25. Merging Visible Light Photoredox and Gold Catalysis
<\/strong>M. N. Hopkinson,* A. Tlahuext-Aca, F. Glorius*
Acc. Chem. Res.<\/em> 2016<\/strong>, 49<\/em>, 2261-2272.
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24. Oxidative Addition to Gold(I) by Photoredox Catalysis: Straightforward Access to Diverse (C,N)-Cyclometalated Gold(III) Complexes<\/strong>
A. Tlahuext-Aca, M. N. Hopkinson, C. G. Daniliuc, F. Glorius*
Chem. Eur. J. <\/em>2016<\/strong>, 22<\/em>, 11587-11592.
(Very Important Paper)
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23. Mild Metal-Catalyzed C\u2013H Activation: Examples and Concepts
<\/strong>T. Gensch, M. N. Hopkinson, F. Glorius,* J. Wencel-Delord*
Chem. Soc. Rev.<\/em> 2016<\/strong>, 45<\/em>, 2900-2936.
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22. Accelerated Discovery in Photocatalysis using a Mechanism-based Screening Method<\/strong>
M. N. Hopkinson, A. G\u00f3mez-Su\u00e1rez, M. Teders, B. Sahoo, F. Glorius*
Angew. Chem. Int. Ed. <\/em>2016<\/strong>, 55<\/em>, 4361-4366; Angew. Chem.<\/em> 2016<\/strong>, 128<\/em>, 4434-4439.
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21. Alkyne Difunctionalization by Dual Gold\/Photoredox Catalysis
<\/strong>A. Tlahuext-Aca, M. N. Hopkinson,\u2020 R. A. Garza-Sanchez,\u2020 F. Glorius*
Chem. Eur. J.<\/em> 2016<\/strong>, 22<\/em>, 5909-5913.
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20. Visible Light-Promoted Trifluoromethylthiolation of Styrenes via Dual Photoredox\/Halide Catalysis<\/strong>
R. Honeker,\u2020 R. A. Garza-Sanchez,\u2020 M. N. Hopkinson,* F. Glorius*
Chem. Eur. J.<\/em> 2016<\/strong>, 22<\/em>, 4395-4399.
(Hot Paper)
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19. Dual Gold\/Photoredox-Catalyzed C(sp)\u2212H Arylation of Terminal Alkynes with Diazonium Salts<\/strong>
A. Tlahuext-Aca,\u2020 M. N. Hopkinson,\u2020 B. Sahoo, F. Glorius*
Chem. Sci.<\/em> 2015<\/strong>, 7<\/em>, 89-93.
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18. External-Photocatalyst-Free Visible-Light-Mediated Synthesis of Indolizines
<\/strong>B. Sahoo,\u2020 M. N. Hopkinson,\u2020 F. Glorius*
Angew. Chem. Int. Ed.<\/em> 2015<\/strong>, 54<\/em>, 15545-15549; Angew. Chem.<\/em> 2015<\/strong>, 127<\/em>, 15766-15770.
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17. Dual Photoredox and Gold Catalysis: Intermolecular Multicomponent Oxyarylation of Alkenes<\/strong>
M. N. Hopkinson, B. Sahoo, F. Glorius*
Adv. Synth. Catal.<\/em> 2014<\/strong>, 356<\/em>, 2794-2800.
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16. An Overview of N-Heterocyclic Carbenes
<\/strong>M. N. Hopkinson, C. Richter, M. Schedler, F. Glorius*
Nature<\/em> 2014<\/strong>, 510<\/em>, 485-496.
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15. Using Rh(III)-Catalyzed C\u2212H Activation as a Tool for the Selective Functionalization of Ketone-Containing Molecules<\/strong>
M. Boultadakis-Arapinis, M. N. Hopkinson, F. Glorius*
Org. Lett.<\/em> 2014<\/strong>, 16<\/em>, 1630-1633.
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14. Dual Catalysis sees the Light: Combining Photoredox with Organo-, Acid and Transition Metal Catalysis<\/strong>
M. N. Hopkinson,\u2020 B. Sahoo,\u2020 J.-L. Li, F. Glorius*
Chem. Eur. J. <\/em>2014<\/strong>, 20<\/em>, 3874-3886.
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13. Combining Gold and Photoredox Catalysis: Visible Light-Mediated Oxy- and Aminoarylation of Alkenes<\/strong>
B. Sahoo, M. N. Hopkinson, F. Glorius*
J. Am. Chem. Soc. <\/em>2013<\/strong>, 135<\/em>, 5505-5508.
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12. Beyond Directing Groups: Transition Metal-Catalyzed C\u2013H Activation of Simple Arenes<\/strong>
N. Kuhl, M. N. Hopkinson, J. Wencel-Delord, F. Glorius*
Angew. Chem. Int. Ed.<\/em> 2012<\/strong>, 51<\/em>, 10236-10254; Angew. Chem. <\/em>2012<\/strong>, 124<\/em>, 10382-10401.
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11. Selective Rh(III)-Catalyzed Cross-Dehydrogenative Coupling of Furan and Thiophene Derivatives<\/strong>
N. Kuhl, M. N. Hopkinson, F. Glorius*
Angew. Chem. Int. Ed. <\/em>2012<\/strong>, 51<\/em>, 8230-8234; Angew. Chem.<\/em> 2012<\/strong>, 124<\/em>, 8354-8358.
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10. Metal-Free Oxidative Fluorination of Phenols with [18<\/sup>F]Fluoride
<\/strong>Z. Gao, Y. H. Lim, M. Tredwell, L. Li, S. Verhoog, M. Hopkinson, W. Kaluza, T. L. Collier, J. Passchier, M. Huiban, V. Gouverneur*
Angew. Chem. Int. Ed.<\/em> 2012<\/strong>, 51<\/em>, 6733-6737; Angew. Chem.<\/em> 2012<\/strong>, 124<\/em>, 6837-6841.
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9. Gold-Catalyzed Coupling Reactions
<\/strong>M. N. Hopkinson, V. Gouverneur
Science of Synthesis Knowledge Updates; Thieme: Stuttgart, (2011), Vol. 2011\/2, Section 3.6.13, p101.
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8. AuI<\/sup>\/AuIII<\/sup> Catalysis: An Alternative Approach for C\u2212C Oxidative Coupling<\/strong>
M. N. Hopkinson,* A. D. Gee, V. Gouverneur*
Chem. Eur. J.<\/em> 2011<\/strong>, 17<\/em>, 8248-8262.
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7. Palladium-Catalyzed Allylic Fluorination<\/strong>
C. Hollingworth, A. Hazari, M. N. Hopkinson, M. Tredwell, E. Benedetto, M. Huiban, A. D. Gee, J. M. Brown,* V. Gouverneur*
Angew. Chem. Int. Ed.<\/em> 2011<\/strong>, 50<\/em>, 2613-2617; Angew. Chem.<\/em> 2011<\/strong>, 123<\/em>, 2661-2665.
(Hot Paper)
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6. Convergent 18<\/sup>F Radiosynthesis: A New Dimension for Radiolabelling
<\/strong>L. Li, M. N. Hopkinson, R. Leuma Yona, R. Bejot, A. D. Gee, V. Gouverneur*
Chem. Sci.<\/em> 2011<\/strong>, 2<\/em>, 123-131.
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5. Gold Catalysis and Fluorine
<\/strong>M. N. Hopkinson, A. D. Gee, V. Gouverneur*
Isr. J. Chem. <\/em>2010<\/strong>, 50<\/em>, 675-690.
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4. Gold-Catalyzed Cascade Cyclization-Oxidative Alkynylation of Allenoates
<\/strong>M. N. Hopkinson, J. E. Ross, G. T. Giuffredi, A. D. Gee, V. Gouverneur*
Org. Lett.<\/em> 2010<\/strong>, 12<\/em>, 4904-4907.
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3. Gold-Catalyzed Diastereoselective Synthesis of \u03b1-Fluoroenones from Propargyl Acetates
<\/strong>M. N. Hopkinson, G. T. Giuffredi, A. D. Gee, V. Gouverneur*
Synlett<\/em> 2010<\/strong>, 2737-2742.
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2. Gold-Catalyzed Intramolecular Oxidative Cross-Coupling of Non-Activated Arenes
<\/strong>M. N. Hopkinson, A. Tessier, A. Salisbury, G. T. Giuffredi, L. E. Combettes, A. D. Gee, V. Gouverneur*
Chem. Eur. J. <\/em>2010<\/strong>, 16<\/em>, 4739-4743.
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1. Diastereoselective Fluorination of Silylated 1,2-Oxazines to Access Fluorinated N,O-Heterocycles<\/strong>
Y.-h. Lam, M. N. Hopkinson, S. J. Stanway, V. Gouverneur*
Synlett <\/em>2007<\/strong>, 3022-3026.
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\u2020 Denotes joint authorship. * Denotes corresponding authorship.<\/em><\/p>\n\n\n\n

<\/p>\n","protected":false},"excerpt":{"rendered":"

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