Michiel

Dr. Michiel L. Petrus

Address Dr. Michiel L. Petrus
Department Chemie, Haus E, Office: 3.039
Ludwig-Maximilians-Universität München
Butenandtstr. 11
81377 München
Germany
Phone +49 (0)89 2180-77626
Room E3.039
E-Mail michiel.petrus@cup.uni-muenchen.de

Research field

My research is mainly in the field of (perovskite) solar cells. I focus on the synthesis of low-cost organic hole transporting materials, the environmental impact, and the influence of moisture on the perovskite stability. Furthermore I study charge transporting properties in small-molecules, polymers and covalent organic frameworks.

In perovskite solar cells, expensive organic materials (such as Spiro-OMeTAD) are used to selectively extract the postive charges from the perovskite and transport these to the electrode. In our group we developed low-cost hole transporting materials by using simple condensation chemistry in which water is the only side-product. In perovskite solar cells our hole transporter materials show comparable performance to state-of-the-art material, however the estimated cost contribution is two orders of magnitude lower. In addition, as a result of the simple chemistry, also the environmental impact is reduced. The results have been published: J. Mater. Chem. A, 2015and J. Mater. Chem. A, 2017

The simplicity of Schiff base condensation chemistry is demonstrated in this video.

Organiser of the E-MRS Fall Meeting symposium 2016 “Organic solar cells including polymers, dyes or perovskites”

Short CV

  • 2014-Present Postdoctoral Research Fellow, LMU Munich, in the group of Prof. Docampo and Prof. Bein.
  • 2010-2014 PhD, Delft University of Technology, Delft, The Netherlands. Group of Prof. Dingemans. Thesis title: Azomethine‐based Donor Materials for Organic Solar Cells.
  • 2008-2010 Master of Science in Molecular design, Synthesis and Catalysis, VU University Amsterdam, University of Amsterdam and Stockholm University, The Netherlands/Sweden.
  • 2005-2010 Bachelor of Applied Science in Organic Chemistry, University of Applied Science Leiden, Leiden, The Netherlands.

Publications

Understanding the Role of Cesium and Rubidium Additives in Perovskite Solar Cells: Trap States, Charge Transport, and Recombination
Yinghong Hu
Eling M. Hutter
Philipp Rieder
Irene Grill
Jonas Hanisch
Meltem F. Aygüler
Alexander G. Hufnagel
Matthias Handloser
Thomas Bein
Achim Hartschuh
Kristoffer Tvingstedt
Vladimir Dyakonov
Andreas Baumann
Tom J. Savenije
Michiel L. Petrus
Pablo Docampo

Adv. Energy. Mater2018, ahead of print
DOI: 10.1002/aenm.201703057

[COVER IMAGE] Design Rules for the Preparation of Low-Cost Hole Transporting Materials for Perovskite Solar Cells with Moisture Barrier Properties
Michiel L. Petrus
Arif Music
Anna C. Closs
Johan C Bijleveld
Maximilian Sirtl
Yinghong Hu
Theo J Dingemans
Thomas Bein
Pablo Docampo

J. Mater. Chem. A 2017, 5, issue 48
DOI: 10.1039/C7TA90281F

Design Rules for the Preparation of Low-Cost Hole Transporting Materials for Perovskite Solar Cells with Moisture Barrier Properties
Michiel L. Petrus
Arif Music
Anna C. Closs
Johan C Bijleveld
Maximilian Sirtl
Yinghong Hu
Theo J Dingemans
Thomas Bein
Pablo Docampo

J. Mater. Chem. A 2017, 5, 25200–25210
DOI: 10.1039/C7TA06452G

Highly stable, phase pure Cs2AgBiBr6 double perovskite thin films for optoelectronic applications
Enrico Greul
Michiel L. Petrus
Andreas Binek
Pablo Docampo
Thomas Bein

J. Mater. Chem. A 2017, 5, 19972
DOI: 10.1039/C7TA06816F

Impact of Rubidium and Cesium Cations on the Moisture Stability of Multiple-Cation Mixed-Halide Perovskites
Yinghong Hu
Meltem F. Aygüler
Michiel L. Petrus
Thomas Bein
Pablo Docampo

ACS Energy Lett., 2017, 2, 2212-2218
DOI: 10.1021/acsenergylett.7b00731

[COVER IMAGE] Perovskite Solar Cells: Capturing the Sun: A Review of the Challenges and Perspectives of Perovskite Solar Cells
Michiel L. Petrus*
Johannes Schlipf*
Cheng Li
Tanaji P. Gujar
Nadja Giesbrecht
Peter Mueller-Buschbaum
Mukundan Thelakkat
Thomas Bein
Sven Huetner
Pablo Docampo

Adv. Energy. Mater. 2017, 7
DOI: 10.1002/aenm.201770085

Capturing the Sun: A Review of the Challenges and Perspectives of Perovskite Solar Cells
Michiel L. Petrus*
Johannes Schlipf*
Cheng Li
Tanaji P. Gujar
Nadja Giesbrecht
Peter Mueller-Buschbaum
Mukundan Thelakkat
Thomas Bein
Sven Huetner
Pablo Docampo

Adv. Energy. Mater. 2017, 7, (16), 1700264
DOI: 10.1002/aenm.201700264

Charge Transfer from Methylammonium Lead Iodide Perovskite to Organic Transport Materials: Efficiencies, Transfer Rates, and Interfacial Recombination
Eline M. Hutter
Jan-Jaap Hofman
Michiel L. Petrus
Michiel Moes
Ruben D. Abellon
Pablo Docampo
Tom J. Savenije

Adv. Energy. Mater. 2017, 1602349
DOI: 10.1002/aenm.201602349

Directional Charge Carrier Transport in Oriented Benzodithiophene Covalent Organic Framework Thin Films
Dana D. Medina*
Michiel L. Petrus*
Askhat Jumabekov*
Johannes Margraf
Simon Weinberger
Julian Rotter
Timothy Clark
Thomas Bein

ACS Nano, 2017, 11 (3), 2706-2713
DOI: 10.1021/acsnano.6b07692

* These authors contributed equally to the work.

The Influence of Water Vapor on the Stability and Processing of Hybrid Perovskite Solar Cells Made from Non-Stoichiometric Precursor Mixtures
Michiel L. Petrus*
Yinghong Hu*
Davide Moia
Philip Calado
Aurélien M. A. Leguy
Piers R.F. Barnes
Pablo Docampo

ChemSusChem, 2016, 9 (18), 2699-2707
DOI: 10.1002/cssc.201600999

* These authors contributed equally to the work.

Unconventional Thin Film Photovoltaics
Chapter 2: Towards Optimum Solution-processed Planar Heterojunction Perovskite Solar Cells
Fabian Hanusch
Michiel Petrus
Pablo Docampo

Unconventional Thin Film Photovoltaics, Chapter 2, 2016, 32-56

ISBN: 978-1-78262-293-2

Hybrid Perovskite/Perovskite Heterojunction Solar Cells
Yinghong Hu
Johannes Schlipf
Mickael Wussler
Michiel L. Petrus
Wolfram Jaegermann
Thomas Bein
Peter Muller-Buschbaum
Pablo Docampo

ACS Nano, 2016, 10 (6), 5999–6007

Recycling Perovskite Solar Cells to Avoid Lead Waste
Andreas Binek*
Michiel L. Petrus*
Niklas Huber
Helen Bristow
Yinghong Hu
Thomas Bein
Pablo Docampo

ACS Appl. Mater. Interfaces, 20168 (20), 12881-12886

* These authors contributed equally to the work.

Charge Transport Through Conjugated Azomethine-based Single Molecules for Optoelectronic Applications
Max Koole
Riccardo Frisende
Michiel L. Petrus
Mickael L. Perrin
Herre S.J. van der Zant
Theo J. Dingemans

Org. Electron., 2016, 34, 38-41

A Low Cost Azomethine-Based Hole Transporting Material for Perovskite Photovoltaics
Michiel L. Petrus
Thomas Bein
Theo J. Dingemans
Pablo Docampo

J. Mater. Chem. A2015, 3, 12159 (open Access)

Device Performance of Small-Molecule Azomethine-Based Bulk Heterojunction Solar Cells
Michiel L. Petrus
Frederik S. F. Morgenstern
Aditya Sadhanala
Richard H. Friend
Neil C. Greenham
Theo J. Dingemans

Chem. Mater., 2015, 27 (8), 2990

Correlating On-Substrate Prepared Electrochromes With Their Solution Processed Counterparts – Towards Validating Polyazomethines as Electrochromes in Functioning Devices
Michael Mulholland
Daminda Navarathne
Michiel L. Petrus
Theo J. Dingemans
W. G. Skene

J. Mater. Chem. C., 2014, 2 (43), 9099

Small-Molecule Azomethines: Organic Photovoltaics via Schiff Base Condensation Chemistry
Michiel L. Petrus
Ricardo K.M. Bouwer
Ugo Lafont
Stavros Athanasopoulos
Neil C. Greenham
Theo J. Dingemans

J. Mater. Chem. A, 2014, 2 (25), 9474 (open access)

Conjugated poly(azomethine)s via simple one-step polycondensation chemistry: synthesis, thermal and optoelectronic properties
Michiel L. Petrus
Ricardo K.M. Bouwer
Ugo Lafont
D.H.K. Murthy
René Kist
Marcus Bohm
Yoann Olivier
Tom J. Savenije
L. D. A. Siebbeles
Neil C. Greenham
Theo J. Dingemans

Polym. Chem., 2013, 4 (15), 4182 (open access)

Enantioselective Synthesis of syn– and anti-1,3-Aminoalcohols via β-Aminoketones and Subsequent Reduction/Dynamic Kinetic Asymmetric Transformation
R. Millet
A. M. Träff
M.L. Petrus
J-E Bäckvall

J. Am. Chem Soc.; 2010, 132, 15182