48. Direct Synthesis of Acyl Fluorides from Carboxylic Acids using Benzothiazolium Reagents
L. M. Maas,† A. Haswell,† R. Hughes, M. N. Hopkinson*
Beilstein J. Org. Chem. 2024, In Press.
(Part of the thematic issue “Organo-fluorine Chemistry VI”; Guest Editor: Prof. D. O’Hagan).
Link to Full Text
47. C−F Bond Insertion: An Emerging Strategy for Constructing Fluorinated Molecules
A. Garg, A. Haswell, M. N. Hopkinson*
Chem. Eur. J. 2024, 30, e202304229.
46. Catalyst-Free Trifluoromethoxylation of Silyl Enol Ethers and Allyl Silanes with Bis(trifluoromethyl)peroxide
L. M. Maas, C. Fasting, P. Voßnacker, N. Limberg, P. Golz, C. Müller, S. Riedel,* M. N. Hopkinson*
Angew. Chem. Int. Ed. 2024, 63, e202317770.
45. Deoxygenative Perfluoroalkylthiolation of Carboxylic Acids with Benzothiazolium Reagents
A. Haswell, M. Tironi, H. Wang, M. N. Hopkinson*
J. Fluorine Chem. 2024, 273, 110231.
(Part of the Special Issue honouring Prof. Dr. Beate Koksch, Freie Universität Berlin – Recipient of the 2021 American Chemical Society Award for Creative Work in Fluorine Chemistry; Editor: J. Thrasher).
44. Formal Insertion of Alkenes Into C(sp3)−F Bonds Mediated by Fluorine-Hydrogen Bonding
A. Garg, N. J. Gerwien, C. Fasting, A. Charlton, M. N. Hopkinson*
Angew. Chem. Int. Ed. 2023, 62, e202302860.
(Hot Paper)
43. A (TD-)DFT Study on Photo-NHC-Catalysis: Photoenolization/Diels-Alder Reaction of Acid Fluorides Catalyzed by N-Heterocyclic Carbenes
A. Mavroskoufis, M. Lohani, M. Weber, M. N. Hopkinson,* J. P. Götze*
Chem. Sci. 2023, 14, 4027-4037.
42. Silver-Catalyzed Nucleophilic Deoxydifluoromethylthiolation of Activated Aliphatic Alcohols with BT-SCF2H
M. Tironi, M. N. Hopkinson*
Eur. J. Org. Chem. 2022, e202101557.
41. Activation of Tetrahydrofuran with 2-((Fluoroalkyl)thio)Benzothiazolium Reagents
L. M. Maas, J. R. Schmid, C. Fasting, P. Voßnacker, A. Mavroskoufis, M. N. Hopkinson*
Tetrahedron 2021, 101, 132512.
(Part of the article collection “Fluorine and Chalcogens”; Guest Editors: E. Magnier & G. Dagousset).
40. Norrish Type II Reactions of Acyl Azolium Salts
A. Mavroskoufis, A. Rieck, M. N. Hopkinson*
Tetrahedron 2021, 100, 132497.
(Part of the article collection “System-Oriented Development of Organocatalysis”; Guest Editor: H. Ohmiya)
Featured in Org. Chem. Highlights (12th September 2022)
39. Deoxygenative Nucleophilic Difluoromethylselenylation of Carboxylic Acids and Alcohols with BT-SeCF2H
M. Tironi, S. Dix, M. N. Hopkinson*
Org. Chem. Front. 2021, 8, 6026-6031.
38. Recent advances in the chemistry and applications of N-heterocyclic carbenes
P. Bellotti, M. Koy, M. N. Hopkinson,* F. Glorius*
Nat. Rev. Chem. 2021, 5, 711-725.
Link to Full Text
Free SharedIt-Link
37. Radical C-H Trifluoromethoxylation of (Hetero)arenes with Bis(trifluoromethyl)peroxide
S. Dix, P. Golz, J. R. Schmid, S. Riedel,* M. N. Hopkinson*
Chem. Eur. J. 2021, 27, 11554-11558.
(Hot Paper)
36. Benzothiazolium Salts as Reagents for the Deoxygenative Perfluoroalkylthiolation of Alcohols
A. Ariamajd,† N. J. Gerwien,† B. Schwabe, S. Dix, M. N. Hopkinson*
Beilstein J. Org. Chem. 2021, 17, 83-88.
(Part of the thematic issue “Organo-fluorine chemistry V”; Guest Editor: D. O’Hagan)
35. Deoxygenative Tri- and Difluoromethylthiolation of Carboxylic Acids with Benzothiazolium Reagents
M. Tironi,† L. M. Maas,† A. Garg, S. Dix, J. P. Götze, M. N. Hopkinson*
Org. Lett. 2020, 22, 8925-8930.
34. Photo-NHC Catalysis: Accessing Ketone Photochemistry with Carboxylic Acid Derivatives
M. N. Hopkinson,* A. Mavroskoufis
Synlett 2021, 32, 95-101.
33. Light-Promoted Organocatalysis with N-Heterocyclic Carbenes
A. Mavroskoufis, M. Jakob, M. N. Hopkinson*
ChemPhotoChem 2020, 4, 5147-5153.
32. Synthesis of Trifluoromethylthiolated Alkenes and Alkynes
M. N. Hopkinson
In Emerging Fluorinated Motifs: Synthesis, Properties and Applications (Eds. D. Cahard, J.-A. Ma); Wiley-VCH: Weinheim, 2020, Volume 2, Chapter 14.
31. N-Heterocyclic Carbene Catalyzed Photoenolization/Diels-Alder Reaction of Acid Fluorides
A. Mavroskoufis, K. Rajes, P. Golz, A. Agrawal, V. Ruß, J. P. Götze, M. N. Hopkinson*
Angew. Chem. Int. Ed. 2020, 59, 3190-3194; Angew. Chem. 2020, 132, 3216-3220.
Link to Full Text in English
Link to Full Text in German
Highlighted in “Synfacts” (B. List, V. K. Singh, Synfacts 2020, 16, 0584)
30. Deoxytrifluoromethylthiolation and Selenylation of Alcohols by using Benzothiazolium Reagents
S. Dix, M. Jakob, M. N. Hopkinson*
Chem. Eur. J. 2019, 25, 7635-7639.
29. An Overview of NHCs
M. N. Hopkinson, F. Glorius
In N-Heterocyclic Carbenes in Organocatalysis (Ed. A. T. Biju); Wiley-VCH: Weinheim, 2019, Chapter 1, p. 1-36.
28. Gold in Photocatalysis
S. Dix, M. N. Hopkinson
In Science of Synthesis: Photocatalysis in Organic Synthesis (Ed. B. König); Thieme: Stuttgart, (2018), Chapter 9.
27. A Radical Revolution for Trifluoromethoxylation
B. Sahoo, M. N. Hopkinson*
Angew. Chem. Int. Ed. 2018, 57, 7942-7944; Angew. Chem. 2018, 130, 8070-8072.
Link to Full Text in English
Link to Full Text in German
Pre-Independent Career (Master, PhD & Postdoc)
26. Diverse Visible-Light-Promoted Functionalizations of Benzotriazoles Inspired by Mechanism-Based Luminescence Screening
M. Teders, A. Gómez-Suárez, L. Pitzer, M. N. Hopkinson, F. Glorius*
Angew. Chem. Int. Ed. 2017, 56, 902-906; Angew. Chem. 2017, 129, 921-925.
Link to Full Text in English
Link to Full Text in German
25. Merging Visible Light Photoredox and Gold Catalysis
M. N. Hopkinson,* A. Tlahuext-Aca, F. Glorius*
Acc. Chem. Res. 2016, 49, 2261-2272.
Link to Full Text
24. Oxidative Addition to Gold(I) by Photoredox Catalysis: Straightforward Access to Diverse (C,N)-Cyclometalated Gold(III) Complexes
A. Tlahuext-Aca, M. N. Hopkinson, C. G. Daniliuc, F. Glorius*
Chem. Eur. J. 2016, 22, 11587-11592.
(Very Important Paper)
Link to Full Text
Highlighted in “Chemistry Views”
23. Mild Metal-Catalyzed C–H Activation: Examples and Concepts
T. Gensch, M. N. Hopkinson, F. Glorius,* J. Wencel-Delord*
Chem. Soc. Rev. 2016, 45, 2900-2936.
Link to Full Text
22. Accelerated Discovery in Photocatalysis using a Mechanism-based Screening Method
M. N. Hopkinson, A. Gómez-Suárez, M. Teders, B. Sahoo, F. Glorius*
Angew. Chem. Int. Ed. 2016, 55, 4361-4366; Angew. Chem. 2016, 128, 4434-4439.
Link to Full Text in English
Link to Full Text in German
Selected for Front Cover
Highlighted in “In the Pipeline” Blog
Highlighted in “Forbes” Magazine
Highlighted in “Chemical & Engineering News”
Highlighted in “chemie.de”
21. Alkyne Difunctionalization by Dual Gold/Photoredox Catalysis
A. Tlahuext-Aca, M. N. Hopkinson,† R. A. Garza-Sanchez,† F. Glorius*
Chem. Eur. J. 2016, 22, 5909-5913.
Link to Full Text
20. Visible Light-Promoted Trifluoromethylthiolation of Styrenes via Dual Photoredox/Halide Catalysis
R. Honeker,† R. A. Garza-Sanchez,† M. N. Hopkinson,* F. Glorius*
Chem. Eur. J. 2016, 22, 4395-4399.
(Hot Paper)
Link to Full Text
Highlighted in “Chemistry Views”
19. Dual Gold/Photoredox-Catalyzed C(sp)−H Arylation of Terminal Alkynes with Diazonium Salts
A. Tlahuext-Aca,† M. N. Hopkinson,† B. Sahoo, F. Glorius*
Chem. Sci. 2015, 7, 89-93.
Link to Full Text
18. External-Photocatalyst-Free Visible-Light-Mediated Synthesis of Indolizines
B. Sahoo,† M. N. Hopkinson,† F. Glorius*
Angew. Chem. Int. Ed. 2015, 54, 15545-15549; Angew. Chem. 2015, 127, 15766-15770.
Link to Full Text in English
Link to Full Text in German
17. Dual Photoredox and Gold Catalysis: Intermolecular Multicomponent Oxyarylation of Alkenes
M. N. Hopkinson, B. Sahoo, F. Glorius*
Adv. Synth. Catal. 2014, 356, 2794-2800.
Link to Full Text
16. An Overview of N-Heterocyclic Carbenes
M. N. Hopkinson, C. Richter, M. Schedler, F. Glorius*
Nature 2014, 510, 485-496.
Link to Full Text
15. Using Rh(III)-Catalyzed C−H Activation as a Tool for the Selective Functionalization of Ketone-Containing Molecules
M. Boultadakis-Arapinis, M. N. Hopkinson, F. Glorius*
Org. Lett. 2014, 16, 1630-1633.
Link to Full Text
14. Dual Catalysis sees the Light: Combining Photoredox with Organo-, Acid and Transition Metal Catalysis
M. N. Hopkinson,† B. Sahoo,† J.-L. Li, F. Glorius*
Chem. Eur. J. 2014, 20, 3874-3886.
Link to Full Text
13. Combining Gold and Photoredox Catalysis: Visible Light-Mediated Oxy- and Aminoarylation of Alkenes
B. Sahoo, M. N. Hopkinson, F. Glorius*
J. Am. Chem. Soc. 2013, 135, 5505-5508.
Link to Full Text
Highlighted in “Nachrichten aus der Chemie”
12. Beyond Directing Groups: Transition Metal-Catalyzed C–H Activation of Simple Arenes
N. Kuhl, M. N. Hopkinson, J. Wencel-Delord, F. Glorius*
Angew. Chem. Int. Ed. 2012, 51, 10236-10254; Angew. Chem. 2012, 124, 10382-10401.
Link to Full Text in English
Link to Full Text in German
11. Selective Rh(III)-Catalyzed Cross-Dehydrogenative Coupling of Furan and Thiophene Derivatives
N. Kuhl, M. N. Hopkinson, F. Glorius*
Angew. Chem. Int. Ed. 2012, 51, 8230-8234; Angew. Chem. 2012, 124, 8354-8358.
Link to Full Text in English
Link to Full Text in German
10. Metal-Free Oxidative Fluorination of Phenols with [18F]Fluoride
Z. Gao, Y. H. Lim, M. Tredwell, L. Li, S. Verhoog, M. Hopkinson, W. Kaluza, T. L. Collier, J. Passchier, M. Huiban, V. Gouverneur*
Angew. Chem. Int. Ed. 2012, 51, 6733-6737; Angew. Chem. 2012, 124, 6837-6841.
Link to Full Text
9. Gold-Catalyzed Coupling Reactions
M. N. Hopkinson, V. Gouverneur
Science of Synthesis Knowledge Updates; Thieme: Stuttgart, (2011), Vol. 2011/2, Section 3.6.13, p101.
Link to Full Text
8. AuI/AuIII Catalysis: An Alternative Approach for C−C Oxidative Coupling
M. N. Hopkinson,* A. D. Gee, V. Gouverneur*
Chem. Eur. J. 2011, 17, 8248-8262.
Link to Full Text
7. Palladium-Catalyzed Allylic Fluorination
C. Hollingworth, A. Hazari, M. N. Hopkinson, M. Tredwell, E. Benedetto, M. Huiban, A. D. Gee, J. M. Brown,* V. Gouverneur*
Angew. Chem. Int. Ed. 2011, 50, 2613-2617; Angew. Chem. 2011, 123, 2661-2665.
(Hot Paper)
Link to Full Text
6. Convergent 18F Radiosynthesis: A New Dimension for Radiolabelling
L. Li, M. N. Hopkinson, R. Leuma Yona, R. Bejot, A. D. Gee, V. Gouverneur*
Chem. Sci. 2011, 2, 123-131.
Link to Full Text
5. Gold Catalysis and Fluorine
M. N. Hopkinson, A. D. Gee, V. Gouverneur*
Isr. J. Chem. 2010, 50, 675-690.
Link to Full Text
4. Gold-Catalyzed Cascade Cyclization-Oxidative Alkynylation of Allenoates
M. N. Hopkinson, J. E. Ross, G. T. Giuffredi, A. D. Gee, V. Gouverneur*
Org. Lett. 2010, 12, 4904-4907.
Link to Full Text
3. Gold-Catalyzed Diastereoselective Synthesis of α-Fluoroenones from Propargyl Acetates
M. N. Hopkinson, G. T. Giuffredi, A. D. Gee, V. Gouverneur*
Synlett 2010, 2737-2742.
Link to Full Text
2. Gold-Catalyzed Intramolecular Oxidative Cross-Coupling of Non-Activated Arenes
M. N. Hopkinson, A. Tessier, A. Salisbury, G. T. Giuffredi, L. E. Combettes, A. D. Gee, V. Gouverneur*
Chem. Eur. J. 2010, 16, 4739-4743.
Link to Full Text
1. Diastereoselective Fluorination of Silylated 1,2-Oxazines to Access Fluorinated N,O-Heterocycles
Y.-h. Lam, M. N. Hopkinson, S. J. Stanway, V. Gouverneur*
Synlett 2007, 3022-3026.
Link to Full Text
† Denotes joint authorship. * Denotes corresponding authorship.
